The sample space is the complete collection of all possible outcomes a scenario can produce. Every outcome that can happen belongs to it, and anything that cannot happen is not included.
Each outcome represents one full, specific result of the situation. Together, these outcomes form the background on which events are defined and probabilities are assigned.
Examples:
Rolling a die → {1, 2, 3, 4, 5, 6}
Tossing two coins → {HH, HT, TH, TT}
Measuring a persons height → all real numbers in an interval (for example, [0, 3] meters)